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Electrochemical
reactions are special Redox
reactions = electron transfer reactions.
........The most important redox reaction is the combustion of fuels (oil, coal, natural gas, wood, petrol). It provides the energy to keep our civilisation going: ........Power stations, automobiles, planes, ships and heating systems are driven by burning fuels. In humans the oxidation of sugars, fats and proteins releases.the ........energy.necessary for life. ........In all these reactions a directelectron transfer takes place from the reducing agent (fuel) to the oxidizing agent (oxygen). In electrochemical reactions an indirect electron transfer from the electron donor (reducing agent) to the electron acceptor (oxidizing agent) moves through a metallic conductor. ........Galvanic cells (Voltaic cells) use a spontaneous chemical reaction to for electrontransfer through the metallic conductor. Chemical energy is converted into electric energy. ........In electrolytic cells electrical work (supplied by a battery) is used as source of energy to drive the reaction into the opposite direction. Electric energy (of the battery) is ........converted into chemical energy:.a metal or hydrogen are formed. Direct
electron transfer reactionsbetween
atoms, molecules or ions are easier to understand than electrochemical
reactions. So three examples of such experiments are presented first:
Devices
for testing and measuring electrochemicals reactions
04 Electric conductivity TESTS with a LED 05 Electric conductivity MEASUREMENT with direct current 06 Electric conductivity MEASUREMENT with alternating current Galvanic cells (Electrochemical cells) 07 Indirect electron transfer from zinc to copper ions 1 08 Indirect electron transfer from zinc to copper ions 2 09 Indirect electron transfer from zinc to copper ions 3: Changing of the electrodes
10 Indirect electron transfer from
copper to copper ions: Concentration
cell 11 Indirect electron transfer between different metals: Electrochemical series Electrolytic cells 12Electrolysis of copper chloride in a Blister 13 Raffination of copper by electrolysis 14. Water drop electrolysis on a white film canister 15 Water electrolysis in a pipette eudiometer, piezo igniter 16. Water electrolysis in two ampoules and tests for the elements Rechargeable
Mono
cells and
batteries
Me02
Zinc and copper in Galvanic Cells and in an orange battery
More
redox reactions (Cola can metals)
back....... ........................first published: 25.10.2001..........................last modification: 03.12.2011
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