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Me03 Alkali metals 3: Differences in reactivity with water
(For experienced chemistry teachers only!
Attention! Alkali metals are extremely corrosive and reactive.
All participants have to wear goggles)

* Left:   Cut TINY (1 x 1 x 0,2 mm) pieces of lithium, sodium and potassium from cleaned and dry metal lumps.
* On a porcellain saucer connect 5 drops to have one big water drop.
* Place the Li the metal beside it, use a wire to push it into the water drop. Clean the lump, dry it carefully.
* Repeat the experiment with sodium and finaly with potassium
* Observations: Li, Na, K react with water, gas bubbles are released, the metals disappears.
* Photo 2: Na reacts more vigorously than Li: It melts, a silvery ball is formed running on the water.
* Photo 3: K is most reactive: It catches fires as soon as it comes into contact with water.
* right:Explanation with the element pyramid:
Li, Na, K are the first members of the element family 1 (Alkali metals):
During their chemical reaction with water each these alkali atom gives 1 electron to a water molecule.
The metal atoms are oxidized  (their positive ions have as may electrons as He, Ne, Ar atoms).
In the same moment each water molecule  is reduced. A hydroxide ion (OH-) and a H atom are left.

The whole reaction is an electron exchange reaction = redox reaction:
 2 Li (Na, K) + 2 H2O ----heat released------> 2 Li(Na,K)OH(aq) + H2(g)
*The increase in reactivity Li<Na<K is related to the increase of atomic radii: The positive nucleus of a K atom has the lowest attraction to the electrons. So one of these electrons can be most easily donated to a water molecule.


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