


Ethyne (acetylene) molecules
can react as an acid by donating
a hydrogen atom without its electron (H+,
"proton") to a base. As an unsaturated
hydrocarbon it is also "hungry" for atoms of other substances like
bromine solution.
What
you need: A device to develop gas (=
injection bottle closed with a stopper which is pierced by the blunted
needle of a 10-ml syringe and by a plastic tubing). Water in the
syringe, a small piece of calcium carbide in the bottle. 1 ml diluted silver
nitrate solution with a drop of conc. ammonia solution (to test for
acidity). 1 ml bromine water (to
test for unsaturated property) made from a potassium bromide
solution by bubbling chlorine through it.
Experiment
to test for acidity (left photo): 1.
Drop water from the syringe on the calcium carbide.
2.
Bubble the gas through the solution with silver nitrate and ammonia
(bottle in the middle of the photo).
Observation:
A solid substance is formed in the right bottle of the photo. The mixture
is transfered on a piece of tissue paper. Middle: A tiny quantity
of the dried solid (aside a match) explodes when the paper is lit on a
tile. Explanation:
C2H2(g) + 2 ([Ag+]
OH-) (aq) ---> Ag2C2(s) + 2 H2O
(Ag2C2(s)=
silver acetylide).
Experiment
with bromine water (Photo 3): 1.
Fill a 10-ml syringe with acetylen.
2.
Slowly bubble the gas through a small bottle with 1 ml bromine water.
3. Close it and shake.
Observation
right
photo: The brown colour and the smell of bromine disappear.
Explanation
using molecule models:
A colourless compound (C2H2Br2)
was formed by bromine and acetylen molecules
C2H2
+ Br2 ----addition----------> C2H2Br2
. This reaction is called addition,
the compound is 1,2-dibromo ethene.
-------->
In the left photo models of acetylene and chlorine molecules made
by welding plastic beads can be seen. Right
photo: Two different models of 1,2-Dibromo ethene. This substance exists
as two isomers: In trans-1,2 dibromo ethene
molecules the two bromine atoms are positioned on different sides of the
C=C plane, in cis-1,2 dibromo ethene they are on the same side.