Bromine
water was decolourized by acetylene in the the last
experiment, because two bromine atoms were added
to one of the double bondings of ethine molecules. In the following experiment
you will mix bromine water with two liquid hydrocarbons: Hexene is unsaturated
like acetylene, hexane is saturated.
*Both hydrocarbons are very inflamable. *Bromine water is poisonous. *Ask
for an adult. * Work outdoors. * Use a tray.
What
you need:
Two injection
bottles with bromine water, dropper bottles with cyclohexane and cyclohexene,
stoppers.
* Experimentleft
photo:Half-fill the bottles with bromine water.
* Add 20 drops of cyclohexane
to the left vial and 20 drops cyclohexene to the right one.
* Close the stoppers, shake
vigorously and wait.
Observation
and explanation cyclohexene right photo, right bottle)
The hydrocarbon floats on
the aqueous solution. Cyclo hexene decolourizes bromine water, bromine
molecules are added:
C6H10(l) + Br2(aq)
--addition--> C6H10Br2(l)
Observation
and explanation cyclohexane right photo, left bottle)
Cyclohexane floats on the
aqueous solution. The colour of bromine concentrates in the upper layer
as the hydrocarbon dissolve better than in water. There is no chemical
reaction.