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Fresco painting Pompeji 1. c.b.Chr |
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salt11 Setting
of lime mortar = chemical reaction with CO2
of air
Lime
mortar is a mixture of slaked lime and water; for plastering a newly
built room sand is added. While this pulp hardens on the wall a chemical
reaction of slaked lime and carbon dioxide of the air takes place. The
product is a hard substance which is calcium carbonate.
Photo 3: Plastering
can be combined with painting of ceilings and walls. The artist "frescos",
which means he paints his portray on the fresh (it.: affreso painting in
the fresh) lime mortar. The setting starts at the interface mortar/air,
covering the painting with a thin transparent layer of solid calcium
carbonate. Such a fresco painting of a young couple from Pompeji dates
back to the 1. century before Christ.


Material
Tray, goggle, gloves, sample
of slaked lime from the prvious experiment, stopper of an infusion bottle,
match for stirring, 3 labeled dropper bottles with water, vinegar and limewater.
Material
1.Transfer the slaked lime
from the previous experiment into the stopper
Add water to make a pulp of lime mortar (Photo 1).
2.Keep it at the air for
some days.
3. Add drops of vinegar
(Photo 2). Hold a drop of limewater above the stopper.
Observations
a)
A hard, brittle substance is formed.
b) After adding a drop of
hydrochloric acid to the setted mortar gas bubbles can be seen.
c) This gas makes a drop
of lime water (placed above it) milky.
Explanation
Calcium hydroxide of the
mortar reacts with the carbon dioxide of the air forming lime stone
Ca(OH)2 + CO2 --setting--> CaCO3
+ H2O
The reaction of acid with
the hardened product proves that the gas was newly built carbon dioxide.
Erklärungen: Beim Erhärten
von Kalkmörtel läuft eine chemische Reaktion ab, die man Abbinden
nennt.
Addition:
Changes at the interface
between a drop of lime water and air are a model for the setting of lime.Ein
Modell für das Abbinden ist die Veränderung eines Tropfens Kalkwasser
an der Luft.
Photo 4: Setting of lime
is the last step of the limestone cycle in industry: Calcium carbonate
(after burning and slaking) is reclaimed here.